General Links and Resources
Advice
and Information about Exams - Important!
Old
Exam I - to get you acquainted with my exams
Spreadsheets
for Illustrating Analytical and Physical Chemistry
By Chapter/Unit
Chapter 10
Chapter
10 Goals -
Information
on Batteries and Corrosion - from the Corrosion Doctors!
Example
of Debye-Huckel Limiting Law versus Experiment - See the limiting law
fail!
Additional
conceptual questions - Similar to those mentioned in class
Solvation
of F and Cl anions by water - 2003 research paper discussing
the orientation of water molecules around F- and Cl-.
The discussion is about structure, but has obvious implications for the
entropy of solvation.
Chapter 24
J.
Phys. Chem. Article on Diffusion -
Animation
of Solvation of NaCl - incidental to a guide to generating graphics
(Universität Bochum)
Simulations
of Solvation - Not electrolytes, but still interesting. (Syracuse
University)
Movie
of Counterflowing molecules - (CalTech)
Random
Walk - Diffusion with and without a current (Universität
Karlsruhe)
Animation
with Instruction - Diffusion and Membrane Potentials (University of
Vermont)
Chapter 25
IUPAC
Chemical Kinetics Database - PDF file of recommended rate constants for use in tropospheric
chemistry
JPL
Data Evaluation #15 - Chemical Kinetics and Photchemical Data for Use
in Atmospheric Studies (PDF file).
NIST
Chemical Kinetics Database - Searchable database of rate constants.
Data has
tabulated, not evaluated.
Consecutive
Reactions worksheet and
Consecutive
Reactions pdf file - PDF file showing variants of Figure 25.13 for three
ratios of ka/kb and with
ka fixed at 103 s-1. This is for
the reaction scheme with the elementary reactions:
A -> I with rate constant kA
I -> Products with rate constant kB
Steady
State Approximation for H2 + Br2 Reaction - PDF file which justifies
the very strange rate law for the H2 + Br2 reaction.
Spreadsheet
for Calculating Termolecular Rate Constants - Using the Troe formalism.
Created by TSD.
Organic Reaction Animations (Brigham Young University)