Faculty Profile
Jiajue Chai

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Assistant Professor

Department of Chemistry
418 Jahn Laboratory

Research

Dr. Jiajue Chai is an atmospheric chemist, with special interests in tracking sources, atmospheric processes and sinks of reactive nitrogen species, and quantitatively understanding their implications for air quality, climate, and human and ecosystem health. To address these questions, his research brings together a novel set of skills including instrumentation, analytical methods, theory and modeling to investigate atmospheric chemistry in both the laboratory and field. His recent work involves characterization of nitrous acid (HONO), nitrogen oxides (NOx=NO+NO2), nitric acid (HNO3) and particulate nitrate in their sources, sinks and atmospheric chemistry in many ways, to constrain their atmospheric budgets and the atmospheric oxidative capacity. Ultimately, the research findings will help predict and mitigate the air quality and climate change. Over the years, Dr. Chai has built extensive collaborations with scientists across the US including those from NASA, NOAA and USDA, as well as numerous institutions. Jiajue's current research work is supported by three ongoing grants from the National Science Foundation.

Perspective postdocs, graduate and undergraduate students who are interested in performing research with Dr. Chai are encouraged to contact Dr. Chai via email (jichai at esf.edu)

Major research themes:

Stable isotopes composition analysis of reactive nitrogen species in various environments
Analytical techniques and instrumentation development (Optical Spectroscopy and Mass Spectroscopy)
Reactive nitrogen cycling in the urban environment
Wildfire smoke chemistry and its impact on urban air quality
Indoor air quality

Professional Experience

2023.1 – now Assistant Professor, Department of Chemistry, SUNY College of Environmental Science and Forestry

2020.1 – 2022.12 Assistant Professor of Research, Department of Earth, Environmental and Planetary Sciences, and Institute at Brown for Environment and Society, Brown University

Education

Postdoctoral training in atmospheric chemistry, biogeochemistry and stable isotopes chemistry, Department of Earth, Environmental and Planetary Sciences, Brown University (2016–2019)

Postdoctoral training in combustion chemistry, School of Engineering, Brown University (2014–2016)

Ph.D. in chemistry (physical, atmospheric, environmental), Department of Chemistry, SUNY ESF (2014)

Selected publications

Complete listing: Google Scholar

Miller, D., Chai, J., Guo, F., Ponce de León, M. A., Ryals, R., Dell, C. J., Karsten, H., Hastings, M. G. Cropland soil nitrogen oxide emissions vary with dairy manure incorporation methods. Agrosystems, Geosciences & Environment, 2024, 7 (2), e20485.
Xiong, Y.; Chai, J.; Mao, H.; Mariscal, N.; Yacovitch, T.; Lerner, B.; Majluf, F.; Canagaratna, M.; Olaguer, E. P.; Huang, Y. Examining the Summertime Ozone Formation Regime in Southeast Michigan Using MOOSE Ground-Based HCHO/NO2 Measurements and F0AM Box Model. Journal of Geophysical Research: Atmospheres 2023, 128 (19), e2023JD038943. https://doi.org/10.1029/2023JD038943.
Zong, Z.; Wang, T.; Chai, J.; Tan, Y.; Liu, P.; Tian, C.; Li, J.; Fang, Y.; Zhang, G. Quantifying the Nitrogen Sources and Secondary Formation of Ambient HONO with a Stable Isotopic Method. Environ. Sci. Technol. 2023. https://doi.org/10.1021/acs.est.3c04886.
Shi, G.; Buffen, A. M.; Hu, Y.; Chai, J.; Li, Y.; Wang, D.; Hastings, M. G. Modeling the Complete Nitrogen and Oxygen Isotopic Imprint of Nitrate Photolysis in Snow. Geophysical Research Letters 2023, 50 (12), e2023GL103778. https://doi.org/10.1029/2023GL103778.
Olaguer, E. P.; Su, Y.; Stroud, C. A.; Healy, R. M.; Batterman, S. A.; Yacovitch, T. I.; Chai, J.; Huang, Y.; Parsons, M. T. The Michigan–Ontario Ozone Source Experiment (MOOSE): An Overview. Atmosphere 2023, 14 (11), 1630. https://doi.org/10.3390/atmos14111630.
Warneke, C. et al. (2023): Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ), Journal of Geophysical Research: Atmospheres, 128, e2022JD037758.
Jordan, C. E. et al. (2022)): Beyond the Ångström Exponent: Probing Additional Information in Spectral Curvature and Variability of In Situ Aerosol Hyperspectral (0.3–0.7 μm) Optical Properties, J. Geophys. Res. Atmos., 127, e2022JD037201.
Chai, J. et al. (2021): Isotopic evidence for dominant secondary production of HONO in near-ground wildfire plumes, Atmos. Chem. Phys., 21, 13077–13098.
Wu, X., Huang, C., Chai, J., & Zhang, F. (2021). Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere. The Journal of Physical Chemistry Letters, 12, 8790-8797.
Wu, X., Hou, Q., Huang, J., Chai, J., & Zhang, F. (2021). Exploring the OH-initiated reactions of styrene in the atmosphere and the role of Van der Waals complex. Chemosphere, 131004.
Walters, W., Song L., Chai, J., Fang, Y., Colombi, N., Hastings, M. G. (2020). Characterizing the spatiotemporal nitrogen stable isotopic composition of ammonia in vehicle plumes. Atmospheric Chemistry and Physics. 20, 11551–11567.
Chai, J., Miller, D. M., Dibb, J, Hastings, M. G. et al. (2019). Isotopic characterization of nitrogen oxides (NOx), nitrous acid (HONO), and nitrate (pNO3−) from laboratory biomass burning during FIREX. Atmospheric Measurement Techniques 12(12), 6303-6317.
Shi, G., Chai, J. (2019). Isotopic effects of nitrate volatilization in snow: a field investigation in Antarctica. Geophysical Research Letters, 46, 3287–3297.
Walters, W., Chai, J., & Hastings, M. G. (2018). Theoretical Phase Resolved Ammonia–Ammonium Nitrogen Equilibrium Isotope Exchange Fractionations: Applications for Tracking Atmospheric Ammonia Gas-to-Particle Conversion. ACS Earth and Space Chemistry. 3(1),79-89.
Miller, D., Chai, J., Guo, F., Dell, C. J., Karsten, H., Hastings, M. G. (2018). Isotopic Composition of in Situ Soil NOx Emissions in Manure-Fertilized Cropland. Geophysical Research Letters, 45(21), 12-058.
Chai, J., Hastings, M. G. (2018). Collection method for isotopic analysis of gaseous nitrous acid. Analytical Chemistry, 90 (1), 830–838.
Chai, J., Goldsmith, C. F. (2017). Rate coefficients for fuel+ NO2: Predictive kinetics for HONO and HNO2 formation. Proceedings of the Combustion Institute, 36(1), 617-626.